AugerScan AES XPS software Tutorial

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AugerScan is RBD Instrument’s widely used software program which acquires and massages data on older Physical Electronics PHI X-ray photoelectron and AES Auger surface analysis systems and components. AugerScan is used in conjunction with the RBD Instruments 147 PC Interface unit. The 147 connects to the PC and provides a hardware interface between the software and the system hardware.

This post will explain all of the features and settings in AugerScan and how to configure the software for your particular system type.

augerscan-pulldown-menus

Beginning with the first pull down at the top of the status bar we have the File menu.

New New acquisition. Acquisition types include Alignment, survey, multiplex and depth profiles. You can also select the technique – XPS, AES or SIMS.
Open Open a previously acquired or saved file. You can save a file without acquiring it, in which case you can use it as a template for acquisitions of common settings.  For example, you may want to make a file called Elastic Peak which would be used to set the sample to analyzer distance when acquiring AES data.
Close Standard Windows command
Save Standard Windows command
Save as Standard Windows command
Import Imports AugerScan 1.X versions into the 3.X format
Export as Text Export file to ASCII format.  The ASCII format can be used for programs such as Excel and is also the format used by CASAXPS to read in AugerScan files.
Export All as Text Exports multiple files to ASCII format.
Export to Quases Export file to Quases formatQuases software download
Export all to Quases Export selected files to Quases format
Export to Multipak Export to older versions of the PHI Multipak format. Most new surface analysis systems use (or offer as an option) CASAXPS for advanced data massage functions.
Print Standard Windows command
Print Preview Standard Windows command
Print Setup Standard Windows command
Page Setup Standard Windows command
Create Reserved for future use, this command was intended for creating a new Windows object. However, Windows has changed so much that this feature is no longer relevant.
Recent Files A list of the most recent files that were opened. Currently this lists the last 4 files.
Exit Exits and closes AugerScan

The next pull down on the status bar is the Edit menu.

Copy Copies the open file to the Windows clip board. This is used to copy and then paste a survey into Word or some other windows program.
Copy as ASCII Copies the data in an ASCII format to the Windows clipboard.  This feature is used to copy and then paste data in Excel or some other windows program.
Paste Pastes the clipboard into another Windows program
Delete Not used
Mark/Track This is a cursor that displays the intersected energy in eV and the counts in the status bar. It is also used to select elements for the atomic concentration calculation for AES data.
Markers Displays the selected markers or endpoints. When selected the element marker will be displayed on the displayed data peak or in table form. When checked, the selection will be included in the atomic concentration calculation.
Select Endpoints Allows the user to select the endpoints used for the atomic concentration calculation. To use – move the cursor to the desired left end point. Press and hold the left mouse button. Drag the cursor to the desired right hand endpoint, release left mouse button.  This feature is helpful for selecting the peak of interest.
Endpoints Displays the selected endpoints
Annotation Standard Windows command
Element Table Tables used for atomic concentration calculation for AES and XPS, for markers only in SIMS. AES table includes sensitivity factors for 3, 5 and 10kV beam voltage. XPS sensitivity factors include peak and area modes for standard 15kV dual anode and monochromator X-ray sources.
Insert New Object Standard Windows command – seldom used command for inserting things like table or pictures into the data display.
Links Reserved for future use.
Object Reserved for future use.

The next pull down on the status bar is the View menu.

Toolbar The toolbars contain Icon shortcuts to commands and dialog boxes. Once you know these shortcuts they are easier to use than the pull down menus. The View Toolbar command allows the user to enable or disable the toolbars:

  • Main
  • Acquisition
  • Region Selection

We recommend that the tool bars are always selected.

Status bar This is the little box at the bottom of the Augerscan window. It displays pertinent information such as the cursor values and the status of data acquisitions.
Zoom The zoom feature allows you to view an area of interest in the data. To use the Zoom feature, move the magnifying glass cursor to the upper left hand corner of the area of interest. Click the left hand mouse button and drag the box to the lower right hand limit of the area that you want to view. Release the left mouse button. You can perform multiple zooms in.
Restore Un-zooms to the original data display.
Raw Data Displays the raw (original) data.
Transformed data Displays the massaged (transformed) data.
Cycles For depth profiles All region selection, selects cycles as the X axis on the displayed data.
Time Displays the depth profile X axis as time.
Depth Displays the depth profile X axis as depth. This is calculated from the sputter rate set in the Electron/Ion gun properties dialog box.
Expand X axis Expands the X axis display to allow room for text or an image.
Options Allows the user to set options for:

  • General
  • Line Style
  • Annotations
  • Fonts
  • Curve fitting
  • Graph

The next pull down on the status bar is the Acquisition menu.

Start Starts the selected acquisition
Stop Stops the acquisition at the end of the next sweep or cycle
Stop Now Stops the acquisition immediately and the data is not saved
Continue Continues the selected acquisition. This is useful if you want to stop a depth profile at an interface and then acquire a survey, then continue the profile.
Settings Displays all of the settings for the selected acquisition.
Edit Allows the user to remove regions or cycles from a depth profile, and edit the lower and upper limits in surveys.
Sample Properties This menu is where user can enter comments for samples. Typically this is used for 8 sample specimen stages on XPS systems.
New Survey Wide range scan, typically 30 to 1030 or 2030eV for AES and 1100 to 0 binding energy for XPS.
New Multiplex Series of narrow surveys, allows the user to acquire data only on the elements of interest.
New Depth Profile A series of multiplexes with combined with sputter etching acquires the elements of interest vs. depth.
New Alignment (peak) Used to set the elastic peak in AES, and to optimize the position of the sample or X-ray source in XPS.  Data is thrown out at the end of each sweep.
New 3 point depth profile For AES only, a 3 point depth profile makes it possible to get more elements into a depth profile than is practical with the standard depth profile. Since there are only 3 points selected per region (rather than the typical 20 to 50 points per region in a standard depth profile) you can get more elements into the same amount of acquisition time. Good for general trends only as a 3 point profile cannot use the atomic concentration calculation.
Technique Select the technique – AES ( Auger Electron Spectroscopy), XPS (X-ray photoelectron spectroscopy) or SIMS (Secondary Ion Mass Spectroscopy)
Options Allows the user to set options related to acquisitions. The most commonly used is the Prompt to Save after acquiring.

The next pull down on the status bar is the Data menu.

Revert to Raw Data Removes all previous data massage functions and restores the display to the original data.
Edit Raw Data A text editor, this command allows the user to edit out data spikes
Differentiate Normalizes background and displays data in peak to peak form.
Smooth Savitzky and Golay smoothing algorithm.
Convert to Counts Data in Augerscan is displayed in counts per second. This command converts the counts per second value to actual counts.
Shift Shifts the data up or down as specified by the use. Useful for compensating for small amounts of sample charging.
Depth Profile Smooth Smoothes Depth profile display. Similar to the data smooth command.
Deconvolute X-ray Line Fourier transform function that sharpens the XPS peaks
Satellite Subtraction Removes satellite peaks from data which improves the resolution (FWHM).
Baseline Removes the background from the selected endpoints.
Curve Fit Used for fitting hypothetical (possible) peaks into existing multiplex data.
Delete Curve Fit Deletes selected curve fit
Atomic Concentration Performs atomic concentration calculation. Peaks and endpoints need to be selected first. If the sensitivity factors are not in the element table you will need to add them before performing this function.
SIMS Relative Sensitivity Factor Used for SIMS data analysis
SIMS Atomic Density Used for SIMS data analysis
Options Set the number of points for smooth and differentiate, list the range for markers and select peak or area for XPS atomic concentrations.

The next pull down on the status bar is the System menu.

Hardware Properties Selects hardware properties for your system type. This is where you tell AugerScan the specific controls that your system has. Depending on the vintage and type of your system, most model numbers are located in the upper left hand corner of the electronic unit.  For card rack type systems, the model numbers are listed on the bottom of the mother board for each board set in the back of the electronics bay. You also set the input (detector), X-ray anode type and energy, and can calibrate the peak positions (scale factor). We provide calibration information with each 147 upgrade.
Multiplier Properties Sets the multiplier voltage for each technique. For AES, the multiplier can be set automatically for different electron beam currents by selecting the appropriate V/F preamp. Select the Preamp Defaults after first setting your preamp type (typically 96A/B) in the Hardware Properties dialog box.
Gun Properties For booking purposes only, this is where the user enters the typical settings for the electron and ion gun. The sputter rate value is used for the atomic concentration depth view.
Diagnostics Used to test the RBD 147 PC interface unit, for most users the DR11 test and DR11 data entry sections are useful for occasional troubleshooting or calibration of electronic components. To run the full diagnostics special jumper cables are needed.
Sputter Simple sputter timer is useful for sputter cleaning samples before analysis.
Ion Gun Control Opens up the ion gun control dialog box for digital ion gun controls such as the 77-070 (04-300 ion gun), 20-520 (Duoplasmatron ion gun) and 11-066/68 (04-303 and 06-350 ion guns).
Stage Control Controls the movement of digitally controlled specimen stages
Neutralizer Control Controls the 04-085 and 04-090 neutralizer
SIMS Positional Alignment Used for mechanically adjusting the SIMS optics to the position of the ion beam.
XPS Mapping Used for 5600, 5700 and 5800 XPS system that have the mapping hardware option. Due to the small count rate at the smallest aperture size this is not really a practical feature. New state of the art imaging XPS systems have much higher count rates while imaging and much better spatial resolution.
Automation Used primarily for digitally controlled specimen stages, this dialog box allows the used to stack up a number of commands and then run all of the commands as a batch.
Enable Batch Feedback Control No longer used.
Disable Batch Feedback control No longer used.

The next pull down on the status bar is the Window menu.

New Window Standard Windows command
Cascade Standard Windows command
Tile Horizontally Standard Windows command
Tile Vertically Standard Windows command
Arrange Icons Standard Windows command
Display All Regions Opens a window for each region in a multiplex or depth profile.  Currently you need to select this option after the acquisition starts or is completed. The next release of AugerScan will have an option for this to happen automatically.
Recent Acquisitions Lists the 4 most recent files.

The next pull down on the status bar is the Help menu.

Help

The original Help system (largely unchanged since Windows 3.1) was phased out in Windows Vista. The context-sensitive help – also known as “what’s this?” or “right-click” help cannot be replaced (this was the information you would typically see for each field in a dialog box, for example). However, for Windows Vista through 8.1, Microsoft does provide separate downloads for the legacy help system; it’s just no longer installed in the operating system.

You can find most of those files on this Microsoft support page (scroll down to “Resolution”) For security reasons, Microsoft no longer supports this help format at all in Windows 10, and there are no third-party solutions available.

However, we’ve translated most of RBD’s help to HTML for both AugerScan and AugerMap. In each case, simply  unzip the file to a convenient folder and run “index.html” in your browser.

augerscan-iconsThe images below list the commands for the shortcut Icons on the Main and Acquisition tool-bars. Once you learn these commands they make it very simple and fast to acquire and massage data.

Augerscan-Icons-vert

Augerscan Shortcut Icons

RBD 147 Interface Unit Program and Test Procedure

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The RBD Instruments 147 PC interface is used to control most older Physical Electronics surface analysis instruments such as X-ray electron spectrometers and Auger electron spectrometers. The 147 connects to a Windows PC via a PCI or PCIe interface card. Most newer PCs provide only one PCI slot and in the near future the only slots available will be PCIe. If you currently have a PCI interface card and switch your 147 to a newer PC you may need a PCIe interface card to replace your current PCI card.  RBD Instruments will be providing a  trade in discount for your existing PCI card if you need to upgrade to the PCIe version. The 147 and RBD Instruments software operate under Windows XP, 7 and 8.  If you will be changing your operating system to Windows 7 or 8 and will also be getting a new PC please contact RBD Instruments if you are uncertain about the compatibility of your RBD PCI interface card.

The test procedure for the 147 interface card is detailed below.  It is not for the faint of heart, but this information is essential if you want to test all 147 functions.  We rarely have any problems with 147 units in the field. If you think that your 147 interface unit may not be functioning properly and need more information than the test procedure below, please contact us at RBD Instruments.

  RBD 147 Program and Test Procedure

Note: If you are checking a board with no chassis be sure to place it on a thick rubber mat over the power supply in another chassis. Be sure that the bottom of the board is not grounded at any point(s). Then connect the power supply to the board and complete the following checks.

Tools required

Function Generator

Oscilloscope

Voltmeter with test leads

Test Cables (located in box labeled 147 Test Cables)

DR11 Test Cable – 40 pin to 40 pin ribbon cable (this is not a standard ribbon cable)

V/F Test Cable – 25 pin female D-sub to 4 – 2 pin female Molex connectors

V/F Test Cable – 2 pin Male Molex to BNC

Pulse Count Test Cable – 6 pin micro fit to BNC

11-065 Remote – 15 pin female D-sub to BNC

DAC Sweep Cable – 9 pin female D-sub to BNC

(2) 15 pin D-sub connector TTL tester

25 pin D-sub I/O port tester

BNC to banana Jack adapter

ISP download cable

PCI Cable – 64 pin ribbon cable

Programming PCI Cards

Note: The untested PCI card will be tested with the 147. If any of the 147 tests fail it will be necessary to determine if the failure is caused by the PCI card or the 147. To do this change out the 147 being tested with a known working 147 and repeat the test that failed. If the test fails again there is probably a problem with the PCI card. If the test succeeds mark the 147 as failed and start testing again with a new 147 using the same PCI card.

1. Turn off computer and remove currently used PCI card.

2. Remove pin 5 from J2 on the new PCI card.

3. Add the small metal piece so that the card can be mounted in a PCI slot. Use 4-40 X ¼” screws and nuts.

4. Attach the ISP cable to the 8 pin connector.

5. Place PCI card in the computer

6. Turn on the computer

7. Run the ISP Daisy Chain Download (ispVM v10 or higher) program and load the PCI card Rev C file.

8. Run Turbo download.

9. Close ISP Daisy Chain Download program and shutdown the computer.

Power Supply Check

1. VERY IMPORTANT, inspect board closely for solder bridges, shorts, missing components, make sure that the screws holding down the 147 are tight, and power connector is attached.

2. Make sure that U70 crystal is in the proper orientation before power is applied. Failure to do so will result in PERMANENT DAMAGE to the 147. The dot on the crystal should be on the front-right side when the board is in the chassis.

3. Attach power cord. Turn 147 on and verify front panel green LED turns on.

4. Using the multimeter, with the test leads, check all voltages at PWR2. They are marked on the board.

Load 147 ISP

1. Turn off 147 and computer.

2. On 147-J10 cut off pin 5. They are numbered on the board from back to front.

3. Make sure that the computer has an RBD PCI card in it.

4. Connect the PCI cable (64 pin ribbon cable) to the PCI card located in the computer.

5. Connect the other end of the PCI cable to 147-J11.

6. Connect ISP download cable to the LPT1 (printer) port on the PC.

7. Connect small end of ISP download cable to 147-J10.

8. Turn on computer.

9. Turn on 147 and make sure that green LED turns on.

10. Run the ISP Daisy Chain Download (ispVM v10 or higher) program.

11. Open the 147 Rev. G in the FILE menu.

12. Click Run Turbo Download button.

13. Verify that under status you see three PASS indicators on the right side and that there are no errors in the “Messages” window.

14. Close ISP Daisy Chain Download program.

15. Turn off 147.

16. Disconnect 147-J10, leave PCI cable (147-J11) attached.

DR11 Ports check

1. Connect the DR11 test cable from DR11A to DR11D. On one connector the red line on the cable will be towards the back of the 147 and on the other connector the red line will be towards the front.

2. Turn on the 147 and open AugerScan.

3. In the SYSTEM menu select DIAGNOSTICS.

4. In the DIAGNOSTICS window find the DR11 box. Select A and click on test. Passed will show next to test if there are no faults with the DR11 port.

5. Shut off the 147.

6. Repeat steps 1 through 5 for DR11B and DR11C.

VF1 Check

1. There are two parts to the V/F test cable. The first part is a 25 pin D-sub connector with 4 wires hanging out labeled V/F 1 through 4, each of the wires has a 2 pin female molex connector attached. The second part is a 2 pin male molex to BNC used to connect the function generator to the V/F input being tested.

2. Connect the first cable to the 147-P2. Connect the second cable to the TTL output of the function generator and the other end to V/F 1 wire of the first cable.

3. Turn on the 147.

4. Open AugerScan and put it in Auger Mode.

5. In the SYSTEM menu choose HARDWARE PROPERTIES. On the AES panel set the input to VF1.

6. In the SYSTEM menu choose MULTIPLIER PROPERTIES. Select the AES panel and turn off Auto EMS.

7. Click the NEW SURVEY button and click ACQUIRE in the dialog box.

8. Set the function generator decade switch to 100 (100Hz) and change the frequency knob from minimum to maximum and back. Do this for each decade from 100Hz up to 1 MHz. As you increase and decrease the input frequency the data in the acquisition window should also increase and decrease. As the frequency is increased look for any sudden drops in the data, this will indicate a failure with the 147

9. If the survey is not complete click the STOP NOW button to stop the acquisition.

10. To verify the 147 is reading the correct frequency, set the function generator to 100 KHz and click the START button. The computer should show a max count of around 100,000.

11. Stop the acquisition and turn off the 147.

12. In the SYSTEM menu choose HARDWARE PROPERTIES. On the AES panel set the input to VF2.

13. Where the test cable from the function generator connects to the V/F1 wire of the other cable disconnect it and attach it to the V/F 2 wire.

14. Turn on the 147.

15. Start a new survey. With the function generator decade switch set to 1M adjust the frequency knob from minimum to maximum. The computer should show the counts go and then back down. This step is used to verify that the input works.

16. Repeat steps 11 through 14 for V/F 3 and V/F 4.

17. Turn off the function generator and the 147. Disconnect 147-P2.

Function Generator ECL Logic Calibration

1. Connect a BNC T to Output on the function generator. Connect one output of the BNC T to an oscilloscope using a BNC Cable. Connect the other output of the BNC T to J2 on the 147 using the Pulse Count Test Cable (BNC to 6 pin microfit).

2. On the Function generator pull the offset knob out and adjust it to midrange. Turn the amplitude knob fully counter clockwise.

3. Turn on the 147, oscilloscope, and function generator.

4. Adjust the amplitude and offset on the function generator to obtain a -1.5V to -0.75V square wave.

5. Turn off the 147, oscilloscope and function generator and remove the cables from the function generator.

Pulse Count Inputs Check

1. Connect the Pulse Count test cable from the function generator output to J2 on the 147.

2. In the SYSTEM menu choose HARDWARE PROPERTIES. On the AES panel set the input to PC1.

3. In the SYSTEM menu choose MULTIPLIER PROPERTIES. Select the AES panel and turn off Auto EMS.

4. Turn on 147.

5. Click the NEW SURVEY button and click ACQUIRE in the dialog box.

6. Set the function generator decade switch to 100 and change the frequency knob from minimum to maximum and back. Do this for each decade from 100Hz up to 1 MHz. As you increase and decrease the input frequency the data in the acquisition window should also increase and decrease. As the frequency is increased look for any sudden drops in the data, this will indicate a failure with the 147.

7. If the survey is not complete click the STOP NOW button to stop the acquisition.

8. To verify the 147 is reading the correct frequency, set the function generator to 100 KHz and click the START button. The computer should show a max count of around 100,000.

9. Stop the acquisition and turn off the 147.

10. Move the test cable from J2 to J3. Turn on the 147.

11. In the SYSTEM menu choose HARDWARE PROPERTIES. On the AES panel set the input to PC2.

12. Start a new survey. With the function generator decade switch set to 1M adjust the frequency knob from minimum to maximum. The computer should show the counts go and then back down. This step is used to verify that the input works.

13. Repeat steps 8 through 11 for J4 and J5, PC3 and PC4 respectively.

14. Turn off the function generator and 147. Disconnect the test cable from the 147.

TTL Ports Check

1. Connect one 15 pin D-sub TTL tester to P3 and another one to P4.

2. Turn on the 147 and open Auger Scan.

3. In the SYSTEM menu select DIAGNOSTICS.

4. In the DIAGNOSTICS window find the TTL I/O box and click on the test button.

5. Passed will show in the TTL I/O box if there are not faults with the TTL ports.

6. Shut off the 147 and remove the test connectors.

Alternate TTL Port Check

Note: This test only tests one TTL line on P3. The TTL line is used as a remote for the 11-065 Ion Gun sputter control. Use this test if using and old version of Auger Scan that does not have the TTL I/O port test or if a there is a failure with the TTL I/O test. At this time this is the only TTL line needed to run a system.

1. Connect 11-065 Remote cable to 147-P3 to a multimeter via a BNC to banana jack adapter.

2. Turn on 147.

3. Open AugerScan.

4. Verify that the multimeter reads 4V. This is the expected setting when the ion gun is off.

5. In AugerScan open SYSTEM menu and choose SPUTTER.

6. Type 0.1 minutes in the dialog box and press start to turn on the ion gun control.

7. Verify that the multimeter reads less than 150mV for 6 seconds and then returns to 4 V.

8. Close AugerScan, turn off 147, and remove the cable from 147-P3.

DAC Sweep Check

1. Connect the DAC Sweep test cable from the 147-J6 to a multimeter via a BNC adapter.

2. Turn on 147 and open AugerScan. Put it in Auger mode.

3. In the SYSTEM menu select HARDWARE PROPERTIES. Select the AES panel and set ANALYZER CONTROL to the radio button for 11-500A OR 20-805 (top one).

4. Click the NEW SURVEY button and in the dialog box set the survey for 0 eV to 3199 eV at 10 or 20 ms. Then click ACQUIRE.

5. The voltage on the multimeter should go linearly from 0 V (for 0 eV) to about 9.37 V (for 3199 eV) as the scan progresses.

6. When the scan finishes, close AugerScan, turn off 147 and disconnect 147-J6.

24 Bit Digital I/O

Note: This test does not work on a Windows 98 computer. It has been tested and found to work with computers running Windows XP, it will probably also work with computers running Windows 2000.

1. Connect the 25 pin D-sub I/O port tester to P1.

2. Turn on the 147.

3. In the SYSTEM menu select DIAGNOSTICS.

4. In the DIAGNOSTICS window find the 24 Bit Digital I/O box and click on the test button.

5. Passed will show in the Diagnostics box if there are no faults with the 24 bit I/O port.

6. Turn off the 147.

7. Move the tester to P5 and repeat steps 2-6.

Alternate 24 Bit Digital I/O

Note: Use this test if it is deemed necessary to test the 24 bit digital I/O and using a Windows 98 OS.

1. Connect the 25 pin D-sub I/O port tester to P1.

2. Turn on the 147 and open Auger Scan.

3. In the SYSTEM menu select DIAGNOSTICS

4. Find the box labeled RBD 147.

5. Using the RBD 147 test will require multiple address and data entries. For write steps enter the address and data and click on write. For read steps enter the address and click read, verify that the data displayed matches the table.

Address

Data

R/W

Address

Data

R/W

02E

8A

W

02E

91

W

028

55

W

02A

55

W

02C

0A

W

02C

A0

W

02C

AA

R

02C

AA

R

02A

55

R

028

55

R

028

AA

W

02A

AA

W

02C

05

W

02C

50

W

02C

55

R

02C

55

R

02A

AA

R

028

AA

R

RBD 147

RBD 147 interface unit and PCI card

X-ray Photoelectron Spectroscopy Tutorial

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X-ray photoelectron spectroscopy (also known as XPS and originally as ESCA), has become one of the most prevalent and useful techniques for surface analysis since the introduction of commercially available instrumentation beginning in the 1960s.  XPS is a UHV surface analysis technique that provides quantifiable elemental and chemical state information from the top 20 to 100 angstroms of surfaces.

Today’s modern XPS systems use monochromatic aluminum X-rays and include the ability to produce real time XPS elemental images with spatial resolution in the range of a few microns.  If you need an XPS system for your research or production testing and can’t afford the $500K to over $1M for a new XPS system, RBD Instruments is your headquarters for refurbished Physical Electronics XPS systems and components.  Contact us for more information.

Below I have listed a number of links to X-ray photoelectron spectroscopy tutorials. They are in no particular order. Collectively, these tutorials provide an in-depth overview of the history, theory and applications for X-ray photoelectron spectroscopy.

Here is new link to an XPS data knowledge base (and a wealth of information on XPS) from Vincent Crist at The XPS library  – https://xpslibrary.com/free-library-membership/     Please support The XPS Library with your donation!

http://www.physics.ucdavis.edu/fadleygroup/BasicConceptsofXPS.pdf

http://mmrc.caltech.edu/SS_XPS/XPS_PPT/XPS_Slides.pdf

http://www.jhu.edu/~chem/fairbr/surfacelab/xps.html

Physical Electronics XPS system

Physical Electronics XPS system